WebSelf-immolative polymers, designed to release a chemical moiety, or a plurality of chemical moieties, upon a pre-determined cleavage event, or sequences of events, are disclosed. The polymers can be simple polymers, comb polymers or branched polymers. Further disclosed are methods of usage, compositions and articles-of-manufactures containing ... Webin smart materials and devices. Inspired by the notion of self-destruction, polymers that depolymerize end-to-end upon triggering have often referred to as self-immolative polymers (SIPs). 8. Other naming conventions including continuous head-to-tail depolymerization. 9. and cascade depolymerization. 10. have also been used.

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WebApr 23, 2008 · Smart polymers are special kinds of polymeric molecules that respond to external stimuli. We have developed a novel smart polymer designed to sequentially … WebSelf-immolative elimination occurs when a molecular system undergoes a spontaneous and irreversible disassembly into its constituent fragments through either an electronic cascade, viaan elimination pathway or, alternatively, where self-immolation is achieved through a cyclisation–elimination event. projected net income formula

Polyglyoxylates: A Versatile Class of Triggerable Self-Immolative ...

http://whitegroup.beckman.illinois.edu/journal%20articles/nrs102.pdf WebJun 1, 2015 · Self-immolative polymers, which degrade by an end-to-end depolymerization mechanism in response to the cleavage of a stabilizing end-cap from the polymer … WebSelf-Immolative RAFT–Polymer Protein Conjugation By applying excess symmetrical nitrophenyl carbonate disulfides to the RAFT end groups, protein-reactive end groups can … projected net irr